Peel pears, leaving the stem in tact. Place pears on their sides in a large saucepan and add butter, Chardonnay, pomegranate juice, and vanilla. Cook on medium heat until the liquid starts to simmer.
Cover and simmer on low heat for 30 minutes. As the pears are cooking, turn gently as needed so they color evenly.
Once the pears are tender, gently remove pears to a plate.
Boil down the remaining liquid until slightly thickened. Spoon reduced sauce over pears and serve with pomegranate seeds.
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